Cellulose ether (CelluloseEther) inogadzirwa kubva ku cellulose kuburikidza ne etherification reaction yeimwe kana akati wandei etherification agents uye yakaoma kugaya. Zvinoenderana neakasiyana maumbirwo emakemikari eether substituents, cellulose ethers inogona kukamurwa kuita anionic, cationic uye nonionic ethers. Ionic cellulose ethers inonyanya kusanganisira carboxymethyl cellulose (CMC); non-ionic cellulose ethers inonyanya kusanganisira methyl cellulose ether (MC), hydroxypropyl methyl cellulose ether (HPMC) uye hydroxyethyl cellulose Ether (HC), nezvimwewo. -ionic mvura-soluble ethers inonyanya kushandiswa muzvigadzirwa zvematope. Muhupo hwe calcium ions, ionic cellulose ether haina kugadzikana, saka haisati yashandiswa mumiti yakaoma-yakavhenganiswa inoshandisa simenti, slaked lime, nezvimwewo sezvinhu zvekusimbisa. Nonionic mvura-soluble cellulose ethers inoshandiswa zvakanyanya muindasitiri yezvivakwa zvekuvaka nekuda kwekumira kwavo kugadzikana uye kuchengetedza mvura.
01. Chemical properties ye cellulose ether
Imwe neimwe cellulose ether ine yakakosha chimiro che cellulose - anhydroglucose chimiro. Mukugadzira cellulose ether, iyo cellulose fiber inotanga kupiswa muine alkaline solution, yozobatwa ne etherifying agent. Iyo fibrous reaction product inocheneswa nekupushwa kuita hupfu hwakafanana nehumwe hunyoro.
Propylene oxide inoshandiswa kuwana hydroxypropyl substituents kuwedzera kune methane chloride mukugadzirwa kweHPMC. Akasiyana-siyana cellulose ether ane akasiyana methyl uye hydroxypropyl substitution ratios, izvo zvinokanganisa kugarisana kwe organic uye tembiricha yegelation ye cellulose ether mhinduro.
Mukugadzirwa kweMC, chete methyl chloride ndiyo inoshandiswa se etherification agent
02. Mamiriro ekushandiswa kwe cellulose ether:
Cellulose ether isiri-ionic semi-synthetic yakakwira molecular polymer, inonyungudika mumvura uye inonyungudika. Iine maitiro akasiyana mumaindasitiri akasiyana. Semuyenzaniso, mune makemikari ekuvaka zvinhu, ine zvinotevera composite mhedzisiro:
①Mushandi wekuchengetedza mvura ②Thickener ③Leveling chivakwa ④Firimu kugadzira zvinhu ⑤Binder
Mune polyvinyl chloride indasitiri, iri emulsifier uye dispersant; muindasitiri yemishonga, ibhinder uye inononoka uye inodzorwa kuburitsa framework material, etc. Nokuti cellulose ine zvakasiyana-siyana zvinokonzerwa nemagetsi, kushandiswa kwayo Munda wacho ndiwowo wakanyanyisa. Izvi zvinotevera zvinotarisa kushandiswa uye kushanda kwe cellulose ether mune zvakasiyana-siyana zvekuvaka.
(1) Mumadziro ekukwenya putty:
Parizvino, mumaguta mazhinji munyika yangu, inodzivirira mvura uye inodzivirira-inodzivirira nharaunda-inoshamwaridzika putty yakakosheswa nevanhu. Iyo inogadzirwa neacetal reaction yevinyl doro uye formaldehyde. Naizvozvo, chinhu ichi chinopedzwa zvishoma nezvishoma nevanhu, uye cellulose ether series zvigadzirwa zvinoshandiswa kutsiva ichi chinyorwa. Kureva kuti, pakuvandudzwa kwezvakatipoteredza zvekuvaka zvivakwa, cellulose parizvino ndiyo chete zvinhu.
Mumvura inodzivirira putty, yakakamurwa kuva marudzi maviri: yakaoma poda putty uye putty paste. Pakati pemhando mbiri idzi dzeputty, yakagadziridzwa methyl cellulose uye hydroxypropyl methyl inofanira kusarudzwa. Iyo viscosity yakatarwa kazhinji iri pakati pe30000-60000cps. Basa guru re cellulose mu putty kuchengetedza mvura, kusungirirana uye lubrication. Sezvo mafomula emaputty evagadziri vakasiyana akasiyana, mamwe ari grey calcium, light calcium, white simenti, nezvimwewo, uye mamwe ari gypsum powder, grey calcium, light calcium, nezvimwewo, saka zvinotsanangurwa, viscosity uye kupinda kwe cellulose mu maitiro maviri akasiyana zvakare. Mari yakawedzerwa inenge 2 ‰-3 ‰. Mukuvaka kwemadziro ekukwenya putty, sezvo chigadziko chemadziro chine imwe dhigirii yekunyudza kwemvura (yero yekunyudza kwemvura yemadziro ezvidhinha ndeye 13%, uye chiyero chemvura chekongiri chiri 3-5%), pamwe chete nekuputika kwekunze kwenyika, kana iyo putty inorasikirwa nemvura nokukurumidza , Ichaita kuti pave nekutsemuka kana kubviswa kwehupfu, izvo zvinoderedza simba reputty. Naizvozvo, kuwedzera cellulose ether kuchagadzirisa dambudziko iri. Asi mhando yekuzadza, kunyanya kunaka kweash calcium yakakoshawo zvakanyanya.
Nekuda kweiyo yakakwira viscosity ye cellulose, iyo buoyancy ye putty inowedzerwa zvakare, uye iyo sagging chiitiko panguva yekuvaka inodzivirirwa zvakare, uye yakanyanya kugadzikana uye kuponesa basa mushure mekukwesha. Izvo zvinodiwa kuwedzera mamwe cellulose ether muupfu putty. Kugadzirwa kwayo uye kushandiswa zviri nyore. Iyo filler uye additives inogona kusanganiswa zvakaenzana muupfu hwakaoma.
(2) Dongo rekongiri:
Mune dhaka rekongiri, kuti uwane simba rekupedzisira, simenti inofanirwa kunge yakazara hydrated. Kunyanya mukuvaka kwezhizha, dhaka rekrete rinorasikirwa nemvura nokukurumidza, uye zviyero zve hydration yakakwana inoshandiswa kuchengetedza uye kusasa mvura. Kuraswa kwezviwanikwa uye kushanda kusingaite, chinhu chakakosha ndechekuti mvura iri pamusoro chete, uye iyo yemukati hydration ichiri isina kukwana, saka mhinduro yedambudziko iri ndeyekuwedzera mvura-inochengetedza agent cellulose kune dhaka kongiri, kazhinji sarudza hydroxypropyl methyl. kana methyl fiber Iyo viscosity yakatarwa iri pakati pe20000-60000cps, uye mari yekuwedzera ndeye 2% -3%. Mwero wekuchengetedza mvura unogona kuwedzerwa kusvika kupfuura 85%. Nzira yekushandiswa mudhaka rekrete ndeyekusanganisa poda yakaoma zvakafanana uye kuiisa mumvura.
(3) Mukupura gypsum, gypsum yakasungwa, uye caulking gypsum:
Nekukurumidza kukura kweindasitiri yekuvaka, kudiwa kwevanhu kwezvinhu zvitsva zvekuvaka kuri kuwedzerawo. Nekuda kwekuwedzera kwekuziva kwevanhu nezvekuchengetedzwa kwezvakatipoteredza uye nekuenderera mberi kwekuvandudzwa kwekuvaka, zvigadzirwa zve cementitious gypsum zvakakura nekukurumidza. Parizvino, zvigadzirwa zvegypsum zvakajairika kupurasita gypsum, bonded gypsum, inlaid gypsum, uye mataira anonamira. Plastering gypsum ndeyemhando yepamusoro yekupurasita zvinhu zvemukati madziro uye sirin'i. Rusvingo rwakanamwa nawo rwakanaka uye rwakatsetseka. Rudzi rutsva rwekuvaka mwenje bhodhi rinonamira chinhu chinonamira chakagadzirwa negypsum sechinhu chekutanga uye kuwedzera zvakasiyana-siyana zvinowedzera. Iyo yakakodzera kusungirirana pakati peakasiyana inorganic kuvaka madziro zvinhu. Haina chepfu, haina kuravira, uye inokurumidza kugadzika. Icho chinhu chinotsigira mapuranga ekuvaka uye kuvaka block; gypsum caulking agent is gap filler pakati pegypsum board uye yekugadziridza filler yemadziro uye makatsemuka.
Izvi zvigadzirwa zvegypsum zvine mutsara wemabasa akasiyana. Pamusoro pebasa regypsum uye mafirita ane hukama, nyaya yakakosha ndeyekuti iyo yakawedzera cellulose ether additives inoita basa rinotungamira. Sezvo gypsum yakakamurwa kuita anhydrous gypsum uye hemihydrate gypsum, gypsum yakasiyana ine mhedzisiro yakasiyana pakuita kwechigadzirwa, saka kukora, kuchengetwa kwemvura uye kunonoka kunoona kunaka kwezvigadzirwa zvekuvaka gypsum. Dambudziko rinowanzoitika rezvinhu izvi nderokuchera uye kuputika, uye simba rekutanga harigoni kusvika. Kugadzirisa dambudziko iri, ndiko kusarudza rudzi rwe cellulose uye nzira yekushandiswa kwekomboni ye retarder. Panyaya iyi, methyl kana hydroxypropyl methyl 30000 inowanzosarudzwa. -60000cps, iyo yekuwedzera mari ndeye 1.5% -2%. Pakati pavo, cellulose inotarisa pakuchengetedza mvura uye kudzoreredza lubrication. Zvisinei, hazvibviri kuvimba ne cellulose ether se retarder, uye zvakakosha kuwedzera citric acid retarder kusanganisa uye kushandisa pasina kukanganisa simba rekutanga.
Kuchengetwa kwemvura kunowanzo reva kuti yakawanda sei mvura inorasika yega pasina kutorwa kwemvura kunze. Kana madziro akanyanya kuoma, kunyura kwemvura uye kubuda kwechisikigo pachigadziko kuchaita kuti zvinhu zvirasikirwe nemvura nekukasira, uye kuputika nekutsemuka kuchaitika zvakare. Iyi nzira yekushandiswa inosanganiswa nehupfu hwakaoma. Kana iwe ukagadzirira mhinduro, tapota tarisa kune nzira yekugadzirira yemhinduro.
(4) Thermal insulation mortar
Insulation mortar imhando nyowani yemukati madziro ekudzivirira zvinhu mudunhu rekuchamhembe. Icho chinhu chemadziro chakagadzirwa nekuisa insulation, dhaka uye binder. Mune ino chinyorwa, cellulose inoita basa rakakosha mukubatanidza uye kuwedzera simba. Kazhinji sarudza methyl cellulose ine viscosity yakakwirira (inenge 10000cps), muyero unowanzo pakati pe2 ‰-3 ‰), uye nzira yekushandiswa yakaoma poda kusanganisa.
(5) interface mumiririri
Sarudza HPNC 20000cps yemushandisi weinterface, sarudza 60000cps kana kupfuura yekunamira mataira, uye tarisa pane gobvu mune interface agent, iyo inogona kuvandudza kusimba kwesimba uye anti-museve simba. Inoshandiswa sechinhu chinochengeta mvura mukubatana kwematiles kudzivirira matiles kubva pakupedza mvura nekukasira nekudonha.
Nguva yekutumira: Kubvumbi-20-2023