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Yiziphi izakhiwo ze-rheological zezinhlelo ze-HPMC thickener?

IHydroxypropyl methylcellulose (HPMC) iyi-polymer eguquguqukayo esetshenziswa kabanzi njengokuqina ezimbonini ezahlukahlukene ezifana nemithi, izimonyo, ukudla, nezinto zokwakha. Ukuqonda izakhiwo ze-rheological zezinhlelo ze-HPMC thickener kubalulekile ekuthuthukiseni ukusebenza kwazo ezinhlelweni ezahlukene.

1. I-Viscosity:

Amasistimu okuqina e-HPMC abonisa ukuziphatha kokushear, okusho ukuthi i-viscosity yawo iyancipha ngokwenyuka kwezinga lokugunda. Lesi sakhiwo sinenzuzo ezinhlelweni zokusebenza lapho isicelo esilula noma ukucutshungulwa kuyadingeka, njengakumapende nama-coatings.

I-viscosity yezixazululo ze-HPMC ithonywa izici ezifana nokugxila kwe-polymer, isisindo samangqamuzana, i-substitution degree, izinga lokushisa, nezinga lokugunda.

Ngamazinga aphansi okugunda, izixazululo ze-HPMC ziziphatha njengoketshezi lwe-viscous olune-viscosity ephezulu, kuyilapho kumazinga aphezulu okugunda, ziziphatha njengoketshezi oluncane lwe-viscous, lwenza lula ukugeleza.

2. Thixotropy:

Thixotropy ibhekisela endaweni yoketshezi oluthile ukuze kubuye i-viscosity yayo lapho imile ngemva kokuba ngaphansi kwengcindezi yokugunda. Izinhlelo ze-HPMC thickener zivame ukubonisa ukuziphatha kwe-thixotropic.

Lapho ingaphansi kwengcindezi yokugunda, amaketanga e-polymer amade aqondana lapho kugeleza khona, ehlisa i-viscosity. Lapho sekuphelile ukucindezelwa kwe-shear, amaketanga e-polymer kancane kancane abuyela ekuqondeni kwawo okungahleliwe, okuholela ekwandeni kwe-viscosity.

Thixotropy iyathandeka ezinhlelweni ezifana nezingubo zokunamathisela kanye ne-adhesives, lapho impahla idinga ukugcina ukuzinza ngesikhathi sokufaka isicelo kodwa igeleza kalula ngaphansi kwe-shear.

3. Yield Stress:

Amasistimu okuqina we-HPMC avame ukuba nengcindezi yesivuno, okuyingcindezi encane edingekayo ukuze kuqalwe ukugeleza. Ngaphansi kwalokhu kucindezeleka, okubalulekile kuziphatha njengokuqinile, okubonisa ukuziphatha okunwebekayo.

Ukucindezelwa kwesivuno kwezixazululo ze-HPMC kuncike ezintweni ezifana nokugxila kwe-polymer, isisindo samangqamuzana, kanye nezinga lokushisa.

Ukucindezeleka kwesivuno kubalulekile ekusetshenzisweni lapho okubalulekile kudinga ukuhlala endaweni ngaphandle kokugeleza ngaphansi kwesisindo saso, njengasezimbozweni eziqondile noma ekumisweni kwezinhlayiya eziqinile kumapende.

4. Ukuzwela kwezinga lokushisa:

I-viscosity yezixazululo ze-HPMC ithonywa izinga lokushisa, i-viscosity ngokuvamile iyancipha njengoba izinga lokushisa likhuphuka. Lokhu kuziphatha kujwayelekile kwezixazululo ze-polymer.

Ukuzwela kwezinga lokushisa kungathinta ukuvumelana nokusebenza kwamasistimu okuqina kwe-HPMC ezinhlelweni ezihlukene, okudinga ukulungiswa ekwakhiweni noma ukucubungula amapharamitha ukuze kugcinwe izakhiwo ezifiselekayo kuwo wonke amabanga ahlukene okushisa.

5. Ukuncika Kwezinga Le-Shear:

I-viscosity yezixazululo ze-HPMC incike kakhulu kuzinga lokugunda, namazinga aphezulu okugunda okuholela ekubonakaleni okuphansi ngenxa yokuqondanisa nokwelula kwamaketanga e-polymer.

Lokhu kuncika kwezinga le-shear kuvame ukuchazwa umthetho-mthetho noma amamodeli e-Herschel-Bulkley, ahlobanisa ingcindezi yokugunda nezinga lokugunda kanye nengcindezi yokukhiqiza.

Ukuqonda ukuncika kwesilinganiso sokugunda kubalulekile ekubikezeleni nasekulawuleni ukuziphatha kokugeleza kwezinhlelo zokujiya ze-HPMC ezinhlelweni ezisebenzayo.

6. I-Concentration Effects:

Ukwandisa ukugxila kwe-HPMC esixazululweni ngokuvamile kuholela ekwandeni kwe-viscosity kanye nengcindezi yokukhiqiza. Lo mphumela wokugxilisa ingqondo ubalulekile ukuze kuzuzwe ukuvumelana okufiselekayo nokusebenza ezinhlelweni ezihlukahlukene.

Kodwa-ke, ekugxilweni okuphezulu kakhulu, izixazululo ze-HPMC zingase zibonise ukuziphatha okufana nejeli, ukwakha isakhiwo senethiwekhi esikhulisa kakhulu i-viscosity kanye nokucindezeleka kwesivuno.

7. Ukuxuba kanye Nokusabalalisa:

Ukuxutshwa okufanele nokuhlakazwa kwe-HPMC kusixazululo kubalulekile ukuze kuzuzwe i-viscosity efanayo kanye nezakhiwo ze-rheological kulo lonke uhlelo.

Ukuhlakazwa okungaphelele noma ukuhlanganisana kwezinhlayiya ze-HPMC kungaholela ku-viscosity engafaniswanga kanye nokusebenza okuxekethile ezinhlelweni ezifana nezingubo zokunamathela nezinamatheliso.

Kungase kusetshenziswe izindlela ezihlukahlukene zokuhlanganisa nezithasiselo ukuze kuqinisekiswe ukuhlakazeka okuphelele nokusebenza kwamasistimu okuqina we-HPMC.

Izici ze-rheological zezinhlelo ze-HPMC thickener, okuhlanganisa i-viscosity, i-thixotropy, ingcindezi yesivuno, ukuzwela kwezinga lokushisa, ukuncika kwezinga le-shear, imiphumela yokugxilisa ingqondo, nokuziphatha kokuxuba/nokuhlakazeka, kudlala indima ebalulekile ekunqumeni ukusebenza kwazo ezinhlelweni ezihlukahlukene. Ukuqonda nokulawula lezi zakhiwo kubalulekile ekwakhekeni kwemikhiqizo esekwe ku-HPMC ngokungaguquguquki, ukuzinza, nokusebenza okufunayo.


Isikhathi sokuthumela: May-08-2024
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