I-Sodium Carboxymethyl Cellulose Solubility
I-sodium carboxymethyl cellulose (CMC) iyi-polymer encibilika emanzini etholakala ku-cellulose, i-polysaccharide yemvelo etholakala ezindongeni zamaseli ezitshalo. Ukunyibilika kwe-CMC emanzini kungenye yezinto zayo ezibalulekile futhi kuthonywa izici ezihlukahlukene, okuhlanganisa izinga lokushintsha (DS), isisindo samangqamuzana, i-pH, izinga lokushisa, nokuyaluza. Nakhu ukuhlolwa kokuncibilika kwe-sodium carboxymethyl cellulose:
1. Iziqu Zokushintsha (DS):
- Izinga lokushintsha libhekisela enanini eliyisilinganiso lamaqembu e-carboxymethyl ngeyunithi ngayinye ye-glucose ochungechungeni lwe-cellulose. Amanani aphezulu e-DS akhombisa izinga elikhulu lokushintshwa kanye nokunyuka kokuncibilika kwamanzi.
- I-CMC enamanani aphezulu e-DS ijwayele ukuba nokuncibilika okungcono kwamanzi ngenxa yokugcwala okuphezulu kwamaqembu e-hydrophilic carboxymethyl eduze kweketango le-polymer.
2. Isisindo se-Molecular:
- Isisindo samangqamuzana e-CMC singaba nomthelela ekuncibilikeni kwayo emanzini. I-CMC yesisindo samangqamuzana ephakeme ingase ibonise izilinganiso zokuphela ezihamba kancane uma ziqhathaniswa namabanga aphansi esisindo samangqamuzana.
- Kodwa-ke, uma sekuqediwe, kokubili isisindo samangqamuzana esiphezulu nesiphansi se-CMC ngokuvamile sakha izixazululo ezinezakhiwo ezifanayo ze-viscosity.
3. pH:
- I-CMC izinzile futhi iyancibilika ngebanga elibanzi le-pH, ngokuvamile ukusuka ku-acidic kuya kwezimo ze-alkaline.
- Nokho, amanani e-pH eyeqisayo angase athinte ukunyibilika nokuzinza kwezixazululo ze-CMC. Isibonelo, izimo ze-asidi zingase zikhiqize amaqembu e-carboxyl, zinciphise ukuncibilika, kuyilapho izimo ze-alkali zingaholela ku-hydrolysis kanye nokuwohloka kwe-CMC.
4. Izinga lokushisa:
- Ukunyibilika kwe-CMC kuvame ukukhuphuka ngezinga lokushisa. Amazinga okushisa aphezulu enza kube lula inqubo yokuqedwa futhi kubangele ukugeleza okusheshayo kwezinhlayiya ze-CMC.
- Kodwa-ke, izixazululo ze-CMC zingase zibe nokuwohloka okushisayo emazingeni okushisa aphakeme, okuholela ekwehleni kwe-viscosity nokuzinza.
5. Ukuyaluza:
- Ukuyaluza noma ukuxuba kuthuthukisa ukuhlakazeka kwe-CMC emanzini ngokwandisa ukuthintana phakathi kwezinhlayiya ze-CMC nama-molecule wamanzi, ngaleyo ndlela kusheshiswe inqubo yokukhipha amanzi.
- Ukuyaluza okwanele kuvame ukudingeka ukuze kufezwe ukuqedwa okuphelele kwe-CMC, ikakhulukazi kumamaki esisindo samangqamuzana aphezulu noma ezixazululweni ezigxilile.
6. Ukugcwala Kasawoti:
- Ukuba khona kukasawoti, ikakhulukazi ama-divalent noma ama-multivalent cations njengama-calcium ions, angathinta ukunyibilika nokuzinza kwezixazululo ze-CMC.
- Ukugxila kukasawoti omningi kungase kuholele ekwakhekeni kwezakhiwo ezingancibiliki noma amajeli, okunciphisa ukunyibilika nokusebenza ngempumelelo kwe-CMC.
7. I-Polymer Concentration:
- Ukunyibilika kwe-CMC nakho kungathonywa ukugcwala kwe-polymer esixazululweni. Ukugxila okuphezulu kwe-CMC kungase kudinge izikhathi ezinde zokuhlakazeka noma ukwanda kokuyaluza ukuze kuzuzwe ukugeleza kwamanzi okuphelele.
Kafushane, i-sodium carboxymethyl cellulose (CMC) ikhombisa ukuncibilika kwamanzi okuhle kakhulu phezu kwezimo eziningi, okuyenza ibe isithako esisebenza ngezindlela eziningi ezimbonini ezahlukahlukene. Ukunyibilika kwe-CMC kuthonywa izici ezifana ne-degree of substitution (DS), isisindo samangqamuzana, i-pH, izinga lokushisa, ukuyaluza, ukugxila kukasawoti, kanye nokugxiliswa kwe-polymer. Ukuqonda lezi zici kubalulekile ekuthuthukiseni ukwakheka nokusebenza kwemikhiqizo esekwe ku-CMC ezinhlelweni ezihlukene.
Isikhathi sokuthumela: Mar-07-2024