Upu autu: hydroxypropyl methyl cellulose; PVC ma le maualuga polymerization tikeri; fa'ata'ita'iga laiti; polymerization; localization.
Le talosaga a Saina hydroxypropyl methylcellulosenai lo le faaulufale mai se tasi i le gaosiga o le PVC ma le maualuga polymerization tikeri na faailoa mai. O aafiaga o ituaiga e lua o le hydroxypropyl methylcellulose i luga o meatotino o le PVC ma le maualuga polymerization tikeri na suʻesuʻeina. O fa'ai'uga na fa'aalia ai e mafai ona sui le hydroxypropyl methyl cellulose i totonu o le atunu'u mo le fa'aulufale mai.
High-degree-of-polymerization PVC resins e faasino ile PVC resins ma le averesi tikeri o le polymerization e sili atu i le 1,700 poʻo se fausaga laʻititi fesoʻotaʻi i le va o molelaʻau. Pe a faatusatusa i resin PVC masani, maualuga-polymerization PVC resin e maualuga le maufetuunaʻi, seti compression laiti, tetee vevela lelei, tetee matua, tetee vaivai ma ofuina tetee. O se mea lelei e suitulaga i le paʻu ma e mafai ona faʻaogaina i taʻavale faʻamaufaʻailoga, uaea ma uaea, faʻamaʻi faʻafomaʻi, ma isi.
O le auala gaosiga o le PVC ma le maualuga o le polymerization e masani lava ona faʻamalolo le polymerization. I le gaosiga o le auala faʻamalolo, o le dispersant o se sui fesoasoani taua, ma o lona ituaiga ma le aofaʻi o le a aʻafia saʻo ai le foliga o le tino, tufatufaina atu o vaega, ma le faʻaogaina o le plasticizer o le resin PVC maeʻa. O faiga fa'asalalau e masani ona fa'aogaina o faiga fa'asalalau polyvinyl ma le hydroxypropyl methylcellulose ma le polyvinyl alcohol composite dispersion systems, ma o lo'o fa'aaogaina e le au gaosi oloa i totonu o le atunu'u.
1 Mea mata'utia ma fa'amatalaga
O mea autu autu ma faʻamatalaga o loʻo faʻaaogaina i le suʻega o loʻo faʻaalia i le Laulau 1. E mafai ona vaʻaia mai le Laulau 1 o le fale hydroxypropyl methylcellulose filifilia i totonu o lenei pepa e ogatasi ma le faʻaulufale mai o le hydroxypropyl methylcellulose, lea e maua ai se mea e manaʻomia muamua mo le suʻega suʻega i lenei. pepa.
2 Su'ega mataupu
2. 1 Sauniuniga ole vaifofo hydroxypropyl methylcellulose
Ave se vaega o le vai deionized, tuu i totonu o se atigipusa ma vevela i le 70 ° C, ma faasolosolo malie ona faaopoopo le hydroxypropyl methylcellulose i lalo o le faʻaosooso faifaipea. O le cellulose e faʻafefe i luga o le vai i le taimi muamua, ona faʻasolosolo malie lea ona faʻasalalau seia oʻo ina faʻafefiloi. Fa'alili le vaifofo ile voluma.
Fuafuaga 1 Mea mata'ina autu ma o latou fa'amatalaga
| Igoa mea mata'utia | Fa'amatalaga |
| Vinyl chloride monomer | Sikoa lelei≥99. 98% |
| Vai fa'asalaina | Amioga≤10. 0 μs/cm, tau pH 5. 00 i le 9. 00 |
| Polyvinyl alcohol A | Fa'ailoga ole ava malosi 78. 5% i le 81. 5%, mea efuefu≤0. 5%, mea fe'avea'i≤5. 0% |
| Polyvinyl alcohol B | Faailoga ole ava malosi 71. 0% i le 73. 5%, viscosity 4. 5 i le 6. 5mPa s, mea fe'avea'i≤5. 0% |
| Polyvinyl alcohol C | Fa'ailoga ole ava malosi 54. 0% i le 57. 0% , viscosity 800 ~ 1 400mPa s, mea mautu 39（. 5% i le 40. 5% |
| Hydroxypropyl methylcellulose A faaulufale mai | Viscosity 40 ~ 60 mPa s, vaega vaega o le methoxyl 28% ~ 30%, vaega vaega o le hydroxypropyl 7% ~ 12%, susu≤5. 0% |
| Hydroxypropyl methylcellulose B ile fale | Viscosity 40 ~ 60 mPa · s, vaega vaega o le methoxyl 28% ~ 30%, vaega vaega o le hydroxypropyl 7% ~ 12%, susu ≤5. 0% |
| Pi(2-ethyl peroxydicarbonate) hexyl ester) | Vaega vaega fa'atele [( 45 ~ 50) ± 1]% |
2. 2 Su'ega metotia
I luga o le 10 L masini su'ega la'ititi, fa'aaoga le hydroxypropyl methylcellulose fa'aulufale mai e fa'atino su'ega fa'ata'ita'iga e fa'amautu ai le fua fa'atatau o le su'ega la'ititi; fa'aaoga le hydroxypropyl methylcellulose i totonu o le atunu'u e sui ai le hydroxypropyl methylcellulose mai fafo mo su'ega; O oloa PVC resin na gaosia e le hydroxypropyl methylcellulose na faʻatusatusaina, ma le mafai ona sui le hydroxypropyl methylcellulose fale na suʻesuʻeina. E tusa ai ma taunuʻuga o le suʻega laʻititi, o le suʻega gaosiga o loʻo faia.
2. 3 Laasaga su'ega
A'o le'i faia le tali, fa'amama le ulo polymerization, tapuni le alavai pito i lalo, fa'aopoopo se aofa'i o vai fa'asalaina, ona fa'aopoopo lea o le fa'asalalau; tapuni le ufiufi ulo, fa'amama pe a uma ona pasia le su'ega o le mamafa o le nitrogen, ona fa'aopoopo lea o le vinyl chloride monomer; pe a uma ona faʻafefeteina malulu, faʻapipiʻi le initiator; Fa'aaogā le vai fe'avea'i e fa'ae'e ai le vevela i totonu o le ulo i le vevela o le tali, ma fa'aopoopo le vaifofo ammonium bicarbonate i se taimi talafeagai i le taimi o lenei fa'agasologa e fetu'una'i ai le tau o le pH o le faiga tali; pe a pa'ū le mamafa o le tali i le mamafa o loʻo faʻamaonia i le fua faʻatatau, faʻaopopo se terminator ma se defoamer, ma faʻamalolo le fofo. O le oloa maeʻa o le PVC resin na maua mai i le centrifugation ma le faʻamago, ma faʻataʻitaʻiina mo le auiliiliga.
2. 4 auala su'esu'e
E tusa ai ma metotia faʻataʻitaʻi talafeagai i tulaga tau atinaʻe, o le numera viscosity, foliga vaaia, mea faʻafefe (e aofia ai le vai) ma le faʻaogaina o le plasticizer o le 100 g PVC resin o le PVC resin maeʻa na tofotofoina ma auʻiliʻili; Ole fua ole lapopoa ole PVC resin na tofotofoina; o le morphology o le PVC resin particles sa matauina i le faʻaogaina o le microscope electron scanning.
3 I'uga ma Talanoaga
3. 1 Iloiloga faʻatusatusa o le lelei o vaega eseese o le PVC resin i le polymerization laʻititi
Lomi 2. E tusa ai ma le metotia suʻega o loʻo faʻamatalaina i le 4, o vaega taʻitasi o laʻititi laʻititi maeʻa PVC resin na faʻataʻitaʻiina, ma o faʻaiʻuga o loʻo faʻaalia i le Laulau 2.
Siata 2 i'uga o vaega eseese o su'ega laiti
| Vaega | Hydroxypropyl methylcellulose | Fa'aaliga manino/(g/mL) | Ole lapopo'a ole fasimea/μm | Viscosity/(mL/g) | Plasticizer absorption o le 100 g PVC resin/g | mea fe'avea'i/% |
| 1# | Fa'aulufale mai | 0.36 | 180 | 196 | 42 | 0.16 |
| 2# | Fa'aulufale mai | 0.36 | 175 | 196 | 42 | 0.20 |
| 3# | Fa'aulufale mai | 0.36 | 182 | 195 | 43 | 0.20 |
| 4# | Aiga | 0.37 | 165 | 194 | 41 | 0.08 |
| 5# | Aiga | 0.38 | 164 | 194 | 41 | 0.24 |
| 6# | Aiga | 0.36 | 167 | 194 | 43 | 0.22 |
E mafai ona vaʻaia mai le Laulau 2: O le faʻaaliga manino, numera viscosity ma le faʻapipiʻiina o le plasticizer o le resini PVC maua e latalata i le faʻaaogaina o cellulose eseese mo suʻega laiti; ole oloa resin maua mai ile fa'aogaina ole hydroxypropyl methylcellulose fa'afale ole fua ole laititi ole laititi ole la'ititi.
Ata 1 o lo'o fa'aalia ai ata SEM o oloa resini PVC na maua mai i le fa'aogaina o le hydroxypropyl methylcellulose eseese.
(1)—O le hydroxypropyl methylcellulose faaulufale mai
(2)—O le hydroxypropyl methylcellulose i totonu o aiga
Fig. 1 SEM o resini gaosia i le 10-L polymerizer i luma o le hydroxypropyl methyl cellulose eseese.
E mafai ona vaʻaia mai le Ata 1 o le fausaga o luga o le PVC resin particles e gaosia e eseese cellulose dispersants e tutusa lelei.
I se aotelega, e mafai ona iloa o le hydroxypropyl methylcellulose i totonu o le atunuu o loʻo faʻataʻitaʻiina i lenei pepa e mafai ona suitulaga i le hydroxypropyl methylcellulose mai fafo.
3. 2 Suʻesuʻega faʻatusatusa o le lelei o le PVC resin ma le maualuga o le polymerization tikeri i le gaosiga o suʻega
Ona o le maualuga o le tau ma le lamatiaga o le suʻega o le gaosiga, e le mafai ona faʻaogaina saʻo le polokalame sui atoatoa o le suʻega laʻititi, o lea o le fuafuaga o le faʻasolosolo malie o le faʻalauteleina o le hydroxypropyl methylcellulose fale i le fua faʻatatau. O fa'ai'uga o su'ega o vaega ta'itasi o lo'o fa'aalia ile Siata 3 o lo'o fa'aalia.
Fuafuaga 3 Fa'ai'uga o su'ega o vaega eseese o gaosiga
| Vaega | m (Saina hydroxypropyl methyl cellulose): m (hydroxypropyl methyl cellulose faaulufale mai) | Fa'aaliga manino/(g/mL) | Numera viscosity/(mL/g) | Plasticizer absorption o le 100 g PVC resin/g | mea fe'avea'i/% |
| 0# | 0:100 | 0.45 | 196 | 36 | 0.12 |
| 1# | 1.25:1 | 0.45 | 196 | 36 | 0.11 |
| 2# | 1.25:1 | 0.45 | 196 | 36 | 0.13 |
| 3# | 1.25:1 | 0.45 | 196 | 36 | 0.10 |
| 4# | 2.50:1 | 0.45 | 196 | 36 | 0.12 |
| 5# | 2.50:1 | 0.45 | 196 | 36 | 0.14 |
| 6# | 2.50:1 | 0.45 | 196 | 36 | 0.18 |
| 7# | 100:0 | 0.45 | 196 | 36 | 0.11 |
| 8# | 100:0 | 0.45 | 196 | 36 | 0.17 |
| 9# | 100:0 | 0.45 | 196 | 36 | 0.14 |
E mafai ona iloa mai le Siata 3 o le fa'aogaina o le hydroxypropyl methyl cellulose e faasolosolo malie lava ona fa'atuputeleina se'ia suia atoa e le hydroxypropyl methyl cellulose le hydroxypropyl methyl cellulose mai fafo. O fa'ailoga autu e pei o le palasitika absorption ma le mamafa manino e le'i fesuisuiai tele, e fa'ailoa mai ai o le hydroxypropyl methylcellulose i totonu o le atunu'u ua filifilia i lenei pepa e mafai ona sui ai le hydroxypropyl methylcellulose mai fafo i le gaosiga.
4 Faaiuga
O le su'ega o le hydroxypropyl methyl cellulose i totonu o le atunu'u i luga o se masini su'esu'e la'ititi 10 L o lo'o fa'aalia ai e mafai ona sui le hydroxypropyl methyl cellulose mai fafo; o fa'ai'uga o su'ega o su'ega o lo'o fa'aalia ai o lo'o fa'aaogaina le hydroxypropyl methyl cellulose ile fale mo le gaosiga o le resini PVC, o fa'ailoga autu o le PVC resin ma le fa'aulufale mai o le hydroxypropyl methyl cellulose e leai se eseesega tele. I le taimi nei, o le tau o le cellulose i totonu o le atunuu e maualalo ifo nai lo le cellulose mai fafo. O le mea lea, afai e faʻaaogaina le cellulose i totonu o le fale i le gaosiga, o le tau o fesoasoani gaosiga e mafai ona faʻaititia tele.
Taimi meli: Nov-04-2022