Ma cellulose ethers ndi gulu lamitundu yosiyanasiyana yochokera ku cellulose, polima wachilengedwe wopezeka m'makoma a cellulose. Amagwiritsidwa ntchito kwambiri m'mafakitale osiyanasiyana chifukwa cha mawonekedwe awo apadera, kuphatikiza kusungunuka mumitundu yosiyanasiyana ya solvents. Kumvetsetsa kusungunuka kwa ma cellulose ethers ndikofunikira kwambiri pamagwiritsidwe ake azamankhwala, chakudya, zomangamanga, ndi magawo ena.
Ma cellulose ethers amapangidwa ndi kusintha kwa cellulose kudzera muzochita za etherification. Mitundu yodziwika bwino ya ma cellulose ethers ndi monga methyl cellulose (MC), ethyl cellulose (EC), hydroxyethyl cellulose (HEC), hydroxypropyl cellulose (HPC), ndi carboxymethyl cellulose (CMC). Mtundu uliwonse umakhala ndi mawonekedwe ake osungunuka kutengera kapangidwe kake ka mankhwala komanso kuchuluka kwa m'malo.
Kusungunuka kwa ma cellulose ethers kumatengera zinthu monga kuchuluka kwa ma polymerization, kuchuluka kwa m'malo, kulemera kwa maselo, komanso mtundu wamagulu olowa m'malo. Nthawi zambiri, ma cellulose ether okhala ndi ma degree ochepera olowa m'malo ndi mamolekyu apamwamba kwambiri sasungunuka pang'ono poyerekeza ndi omwe ali ndi ma degree apamwamba olowa m'malo ndi mamolekyu otsika.
Chimodzi mwazinthu zofunikira kwambiri za cellulose ethers ndikutha kusungunula mumitundu yosiyanasiyana ya zosungunulira, kuphatikiza madzi, zosungunulira za organic, ndi zakumwa zina za polar komanso zopanda polar. Kusungunuka m'madzi ndi gawo lalikulu la ma cellulose ethers ambiri ndipo ndizofunikira kwambiri pazamankhwala, chakudya, ndi zinthu zosamalira anthu.
Ma cellulose ethers osungunuka m'madzi monga HEC, HPC, ndi CMC amapanga mayankho omveka bwino, owoneka bwino akamwazikana m'madzi. Mayankho awa amawonetsa machitidwe a pseudoplastic, kutanthauza kuti kukhuthala kwawo kumachepa chifukwa cha kumeta ubweya, kuwapangitsa kukhala oyenera kugwiritsidwa ntchito ngati zolimbitsa thupi, zolimbitsa thupi, ndi opanga mafilimu muzakudya ndi mankhwala.
Kusungunuka kwa ma cellulose ethers mu zosungunulira za organic kumadalira kapangidwe kawo kamankhwala ndi polarity ya zosungunulira. Mwachitsanzo, MC ndi EC zimasungunuka mumitundu yambiri yamafuta osungunulira, kuphatikiza acetone, ethanol, ndi chloroform, chifukwa cha kutsika kwawo m'malo ndi mawonekedwe a hydrophobic. Zinthu izi zimawapangitsa kukhala ofunikira pakugwiritsa ntchito monga zokutira, zomatira, ndi njira zoperekera mankhwala zoyendetsedwa bwino.
HEC ndi HPC, omwe ali ndi magulu a hydroxyethyl ndi hydroxypropyl, motero, amawonetsa kusungunuka kwamphamvu mu zosungunulira za polar organic monga ma alcohols ndi glycols. Ma cellulose ethers nthawi zambiri amagwiritsidwa ntchito ngati zowonjezera komanso zosintha za rheology muzodzoladzola komanso zosamalira anthu, komanso mu utoto ndi zokutira zokhala ndi madzi.
CMC imasungunuka m'madzi ndi zosungunulira zina za polar chifukwa cha zolowa m'malo mwa carboxymethyl, zomwe zimapereka kusungunuka kwamadzi ku tcheni cha polima. Amagwiritsidwa ntchito kwambiri ngati thickening agent, stabilizer, ndi emulsifier muzakudya, mankhwala, komanso ntchito zamafakitale.
Kusungunuka kwa ma cellulose ethers kungakhudzidwenso ndi zinthu zakunja monga kutentha, pH, ndi kupezeka kwa mchere kapena zowonjezera zina. Mwachitsanzo, kuwonjezera ma electrolyte monga sodium chloride kapena calcium chloride kungachepetse kusungunuka kwa ma cellulose ethers osungunuka m'madzi polimbikitsa kuphatikizika kwa polima kapena mvula.
Ma cellulose ethers amawonetsa zinthu zosiyanasiyana zosungunuka zomwe zimawapangitsa kukhala zowonjezera m'mafakitale osiyanasiyana. Kuthekera kwawo kusungunula m'madzi, zosungunulira organic, ndi zakumwa za polar kumathandizira kugwiritsa ntchito mosiyanasiyana kuyambira pakupanga mankhwala kupita ku zida zomangira. Kumvetsetsa khalidwe la kusungunuka kwa ma cellulose ethers ndikofunikira kuti muwongolere magwiridwe antchito awo pazinthu zosiyanasiyana.
Nthawi yotumiza: Apr-24-2024